Growth of a Highly Porous Coordination Polymer on a Macroporous Polymer Monolith Support for Enhanced Immobilized Metal Ion Affinity Chromatographic Enrichment of Phosphopeptides

2014 ◽  
Vol 24 (37) ◽  
pp. 5790-5797 ◽  
Author(s):  
Adeela Saeed ◽  
Fernando Maya ◽  
Dianne J. Xiao ◽  
Muhammad Najam-ul-Haq ◽  
Frantisek Svec ◽  
...  
Keyword(s):  
Coordination Polymer ◽  
Metal Ion ◽  
Polymer Monolith ◽  
Porous Coordination Polymer ◽  
Highly Porous

Metallic and bimetallic nanocatalysts incorporated into highly porous coordination polymer MIL-101

2009 ◽  
Vol 19 (41) ◽  
pp. 7625 ◽  
Author(s):  
M. Samy El-Shall ◽  
Victor Abdelsayed ◽  
Abd El Rahman S. Khder ◽  
Hassan M. A. Hassan ◽  
Hani M. El-Kaderi ◽  
...  
Keyword(s):  
Coordination Polymer ◽  
Porous Coordination Polymer ◽  
Bimetallic Nanocatalysts ◽  
Highly Porous

Homochiral porous coordination polymer of EuIII for metal ion sensing and enantioselective adsorption

CrystEngComm ◽  
2022 ◽  
Author(s):  
Yingling Dong ◽  
Rui Chen ◽  
Xu Zhu ◽  
Caoyuan Niu ◽  
Benlai Wu ◽  
...  
Keyword(s):  
Coordination Polymer ◽  
Metal Ion ◽  
Three Dimensional ◽  
Organic Ligand ◽  
Enantiomerically Pure ◽  
Ion Sensing ◽  
Enantioselective Adsorption ◽  
Metal Ion Sensing ◽  
Porous Coordination Polymer

A novel three-dimensional homochiral porous coordination polymer was obtained by combining luminescent component Eu(III) with enantiomerically pure semirigid triangular organic ligand derived from (L)-α-leucine. Remarkably, it not only exhibited photoluminescence...

scholarly journals Pyrene Carboxylate Ligand Based Coordination Polymers for Microwave-Assisted Solvent-Free Cyanosilylation of Aldehydes

Molecules ◽  
2021 ◽  
Vol 26 (4) ◽  
pp. 1101
Author(s):  
Anirban Karmakar ◽  
Anup Paul ◽  
Elia Pantanetti Sabatini ◽  
M. Fátima C. Guedes da Silva ◽  
Armando J. L. Pombeiro
Keyword(s):  
Coordination Polymer ◽  
Single Crystal ◽  
Coordination Polymers ◽  
Metal Ion ◽  
Solvent Free ◽  
Lewis Acidity ◽  
Carboxylate Ligand ◽  
X Ray Diffraction ◽  
X Ray ◽  
Microwave Assisted

The new coordination polymers (CPs) [Zn(μ-1κO1:1κO2-L)(H2O)2]n·n(H2O) (1) and [Cd(μ4-1κO1O2:2κN:3,4κO3-L)(H2O)]n·n(H2O) (2) are reported, being prepared by the solvothermal reactions of 5-{(pyren-4-ylmethyl)amino}isophthalic acid (H2L) with Zn(NO3)2.6H2O or Cd(NO3)2.4H2O, respectively. They were synthesized in a basic ethanolic medium or a DMF:H2O mixture, respectively. These compounds were characterized by single-crystal X-ray diffraction, FTIR spectroscopy, thermogravimetric and elemental analysis. The single-crystal X-ray diffraction analysis revealed that compound 1 is a one dimensional linear coordination polymer, whereas 2 presents a two dimensional network. In both compounds, the coordinating ligand (L2−) is twisted due to the rotation of the pyrene ring around the CH2-NH bond. In compound 1, the Zn(II) metal ion has a tetrahedral geometry, whereas, in 2, the dinuclear [Cd2(COO)2] moiety acts as a secondary building unit and the Cd(II) ion possesses a distorted octahedral geometry. Recently, several CPs have been explored for the cyanosilylation reaction under conventional conditions, but microwave-assisted cyanosilylation of aldehydes catalyzed by CPs has not yet been well studied. Thus, we have tested the solvent-free microwave-assisted cyanosilylation reactions of different aldehydes, with trimethylsilyl cyanide, using our synthesized compounds, which behave as highly active heterogeneous catalysts. The coordination polymer 1 is more effective than 2, conceivably due to the higher Lewis acidity of the Zn(II) than the Cd(II) center and to a higher accessibility of the metal centers in the former framework. We have also checked the heterogeneity and recyclability of these coordination polymers, showing that they remain active at least after four recyclings.

Guest exchange dynamics in a flexible bilayer porous coordination polymer

2012 ◽  
Vol 16 ◽  
pp. 65-69 ◽  
Author(s):  
Shuyun Wang ◽  
Jingxin Ma ◽  
Lina Li ◽  
Tianliang Chen ◽  
Zhihua Sun ◽  
...  
Keyword(s):  
Coordination Polymer ◽  
Porous Coordination Polymer

scholarly journals Recognition of 1,3-Butadiene by a Porous Coordination Polymer

2016 ◽  
Vol 128 (44) ◽  
pp. 13988-13992 ◽  
Author(s):  
Keisuke Kishida ◽  
Yoshikuni Okumura ◽  
Yoshihiro Watanabe ◽  
Megumi Mukoyoshi ◽  
Silvia Bracco ◽  
...  
Keyword(s):  
Coordination Polymer ◽  
Porous Coordination Polymer

Coordinatively Immobilized Monolayers on Porous Coordination Polymer Crystals

2010 ◽  
Vol 122 (31) ◽  
pp. 5455-5458 ◽  
Author(s):  
Mio Kondo ◽  
Shuhei Furukawa ◽  
Kenji Hirai ◽  
Susumu Kitagawa
Keyword(s):  
Coordination Polymer ◽  
Polymer Crystals ◽  
Porous Coordination Polymer
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