scholarly journals Porous Materials: Massive Anisotropic Thermal Expansion and Thermo-Responsive Breathing in Metal-Organic Frameworks Modulated by Linker Functionalization (Adv. Funct. Mater. 48/2013)

2013 ◽  
Vol 23 (48) ◽  
pp. 5966-5966 ◽  
Author(s):  
Sebastian Henke ◽  
Andreas Schneemann ◽  
Roland A. Fischer
Keyword(s):  
Thermal Expansion ◽  
Porous Materials ◽  
Metal Organic Frameworks ◽  
Anisotropic Thermal Expansion ◽  
Metal Organic

Negative, anisotropic thermal expansion in monolithic thin films of crystalline metal-organic frameworks

2016 ◽  
Vol 222 ◽  
pp. 241-246 ◽  
Author(s):  
Zhengbang Wang ◽  
Peter G. Weidler ◽  
Carlos Azucena ◽  
Lars Heinke ◽  
Christof Wöll
Keyword(s):  
Thin Films ◽  
Thermal Expansion ◽  
Metal Organic Frameworks ◽  
Anisotropic Thermal Expansion ◽  
Metal Organic ◽  
Crystalline Metal

scholarly journals Assessing negative thermal expansion in mesoporous metal–organic frameworks by molecular simulation

2019 ◽  
Vol 7 (41) ◽  
pp. 24019-24026 ◽  
Author(s):  
Jack D. Evans ◽  
Johannes P. Dürholt ◽  
Stefan Kaskel ◽  
Rochus Schmid
Keyword(s):  
Thermal Expansion ◽  
Porous Materials ◽  
Molecular Simulation ◽  
Mechanical Stability ◽  
Metal Organic Frameworks ◽  
Negative Thermal Expansion ◽  
Molecular Simulations ◽  
Considerable Effect ◽  
Metal Organic ◽  
Mesoporous Metal

Molecular simulations reveal that mesoporous metal–organic frameworks display large volumetric negative thermal expansion, which has a considerable effect on mechanical stability, outlining an alternative application for these ultra-porous materials.

Smart metal organic frameworks: Focus on cancer treatment

2021 ◽  
Author(s):  
Monir Falsafi ◽  
Amir Shokooh Saljooghi ◽  
Khalil Abnous ◽  
Seyed Mohammad Taghdisi ◽  
Mohammad Ramezani ◽  
...  
Keyword(s):  
Drug Delivery ◽  
Cancer Treatment ◽  
Porous Materials ◽  
Metal Clusters ◽  
Metal Organic Frameworks ◽  
Controlled Systems ◽  
Metal Organic

Metal–organic frameworks (MOFs), as a prominent category of hybrid porous materials constructed from metal clusters or ions plus organic linkers, have been broadly employed as controlled systems of drug delivery...

scholarly journals Unravelling thermal stress due to thermal expansion mismatch in metal–organic frameworks for methane storage

2021 ◽  
Author(s):  
Jelle Wieme ◽  
Veronique Van Speybroeck
Keyword(s):  
Thermal Expansion ◽  
Thermal Stress ◽  
Pressure Coefficient ◽  
Metal Organic Frameworks ◽  
Methane Storage ◽  
Thermal Expansion Mismatch ◽  
Thermal Pressure ◽  
Temperature Changes ◽  
Metal Organic ◽  
The Impact

Thermal stress is present in metal–organic frameworks undergoing temperature changes during adsorption and desorption. We computed the thermal pressure coefficient as a proxy for this phenomenon and discuss the impact of thermal expansion mismatch.

scholarly journals Porphyrin and phthalocyanine-based Metal Organic Frameworks beyond metal-carboxylates

2020 ◽  
Author(s):  
Siddhartha De ◽  
Thomas Devic ◽  
Alexandra Fateeva
Keyword(s):  
Porous Materials ◽  
Metal Organic Frameworks ◽  
Metal Carboxylates ◽  
Natural Systems ◽  
Metal Organic

Given the ubiquitous role of porphyrins in natural systems, these molecules and related derivatives such as phthalocyanines are fascinating building units to achieve functional porous materials. Porphyrin-based MOFs have been...

Separation of C2Hydrocarbons by Porous Materials: Metal Organic Frameworks as Platform

2014 ◽  
Vol 35 (1) ◽  
pp. 18-38 ◽  
Author(s):  
Debasis Banerjee ◽  
Jun Liu ◽  
Praveen K. Thallapally
Keyword(s):  
Porous Materials ◽  
Metal Organic Frameworks ◽  
Metal Organic

Microporous lanthanide metal-organic frameworks

2012 ◽  
Vol 32 (2-4) ◽  
pp. 81-100 ◽  
Author(s):  
Yao Chen ◽  
Shengqian Ma
Keyword(s):  
Optical Properties ◽  
Metal Ions ◽  
Porous Materials ◽  
Chemical Sensing ◽  
Metal Organic Frameworks ◽  
Current Status ◽  
Multifunctional Materials ◽  
Metal Organic ◽  
Lanthanide Metal ◽  
Solvent Adsorption

AbstractMicroporous metal-organic frameworks (MOFs) based on lanthanide metal ions or clusters represent a group of porous materials, featuring interesting coordination, electronic, and optical properties. These attractive properties in combination with the porosity make microporous lanthanide MOFs (Ln-MOFs) hold the promise for various applications. This review is to provide an overview of the current status of the research in microporous Ln-MOFs, and highlight their potential as types of multifunctional materials for applications in gas/solvent adsorption and separation, luminescence and chemical sensing and catalysis.

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