Room Temperature Oxalic Acid‐Catalyzed, Ambient Pressure Dried, and Cost‐Effective Synthesis of Polybenzoxazine Aerogels for Thermal Insulation

2020 ◽  
pp. 2000856
Author(s):  
Yunyun Xiao ◽  
Liangjun Li ◽  
Sizhao Zhang ◽  
Junzong Feng ◽  
Yonggang Jiang ◽  
...  
Keyword(s):  
Oxalic Acid ◽  
Thermal Insulation ◽  
Room Temperature ◽  
Ambient Pressure ◽  
Cost Effective ◽  
Effective Synthesis ◽  
Acid Catalyzed

scholarly journals Annealing and doping concentration effects on Y2O3: Sm3+ nanopowder obtained by self-propagation room temperature reaction

2013 ◽  
Vol 45 (3) ◽  
pp. 323-329 ◽  
Author(s):  
S. Culubrk ◽  
V. Lojpur ◽  
V. Djordjevic ◽  
M.D. Dramicanin
Keyword(s):  
Room Temperature ◽  
Emission Spectra ◽  
Cost Effective ◽  
Ion Concentration ◽  
Temperature Reaction ◽  
Concentration Effects ◽  
Tem Analysis ◽  
Forbidden Transition ◽  
Effective Synthesis ◽  
Post Synthesis

In this report, structure, morphology and luminescence of Y2O3:Sm3+ nanoparticles prepared by self-propagating room temperature reaction are presented. This new, simple and cost effective synthesis allows obtaining desired phase composition by mixing appropriate amounts of yttrium and samarium nitrates together with sodium hydroxide. A set of samples is prepared with different Sm3+ concentrations (0.1, 0.2, 0.5, 1 and 2 at %) in order to observe changes of luminescence properties. Also, effects of post synthesis annealing at several temperatures (600?C, 800?C and 1100?C) are analyzed. For all samples X-ray diffraction showed that powders have cubic bixbyite structure (Ia-3), and TEM analysis showed particles of less than 100 nm. Luminescence emission spectra clearly show peaks characteristic for electronic spin-forbidden transition of Sm3+ ions 4G5/2?6H5/2, 6H7/2 and 6H9/2 centered at 578, 607 and 654 nm, respectively. Emission lifetime values decrease with Sm3+ ion concentration increment, from 1.94 ms for 0.1 at% to 0.97 ms for 2 at%. In addition, enlargement of lifetime value is observed when thermal treatment is done at the highest temperature due to the elimination of luminescence quenching species from the surface of particles.

scholarly journals Cost-Effective Additive Manufacturing of Ambient Pressure-dried Silica Aerogel

2020 ◽  
pp. 1-32
Author(s):  
Zipeng Guo ◽  
Ruizhe Yang ◽  
Tianjiao Wang ◽  
Lu An ◽  
Shenqiang Ren ◽  
...  
Keyword(s):  
Thermal Insulation ◽  
Silica Aerogel ◽  
Processing Time ◽  
Ambient Pressure ◽  
Cost Effective ◽  
Supercritical Drying ◽  
Insulation Material ◽  
Market Demand ◽  
Insulation Property ◽  
Insulation Performance

Abstract The conventional manufacturing processes of aerogel insulation material is largely relying on the supercritical drying, which suffers from issues of massive energy consumption, high-cost equipment, and prolonged processing time. With the consideration of large market demand of the aerogel insulation material in the next decade, a low-cost and scalable fabrication technique is highly desired. In this paper, a direct ink writing (DIW) method is used to three-dimensionally fabricate the silica aerogel insulation material, followed by room-temperature and ambient pressure drying. Compared to the supercritical drying and freeze-drying, the reported method significantly reduces the fabrication time and costs. The cost-effective DIW technique offers the capability to print complex hollow internal structures, coupled with the porous structure, is found to be beneficial to the thermal insulation property. The addition of fiber to the ink assures the durability of the fabricated product, without sacrificing the thermal insulation performance. The foam ink preparation methods and the printability are demonstrated in this paper, along with the printing of complex three-dimensional geometries. The thermal insulation performance of the printed objects is characterized, and the mechanical properties are also examined. The proposed approach is found to have 56% reduction in the processing time. The printed silica aerogels exhibit a low thermal conductivity of 0.053 W m−1 K−1.

Room Temperature Synthesis of Magnetite Particles by an Oil Membrane Layer-Assisted Reverse Co-Precipitation Approach

2021 ◽  
Vol 1162 ◽  
pp. 41-46
Author(s):  
Uripto Trisno Santoso ◽  
Abdullah ◽  
Dwi Rasy Mujiyanti ◽  
Dahlena Ariyani ◽  
Joyo Waskito
Keyword(s):  
Room Temperature ◽  
Cost Effective ◽  
Inert Gases ◽  
Precipitation Method ◽  
Ambient Atmosphere ◽  
Membrane Layer ◽  
Naoh Solution ◽  
Effective Synthesis ◽  
Magnetite Particles ◽  
Co Precipitation

Reverse co-precipitation (RCP) in ambient atmosphere is one of the strategies to produce magnetite nanoparticles in a rapid, simple, and cost-effective synthesis route without applying temperature surfactants or inert gases. However, RCP of ferrous/ferric blended salt in sodium hydroxide (NaOH) solution in an oxidizing medium produced of maghemite as a dominant phase rather than magnetite because of the oxidation of Fe2+ to Fe3+ happened. Based on this background, an oil membrane layer-assisted reverse co-precipitation approach has been examined to synthesis of magnetite in ambient atmosphere at room temperature. The result showed that although addition of benzene as an oil membrane layer was effective to prevent oxidation of magnetite to maghemite, but the magnetite particle size for the samples from the oil membrane layer-assisted reverse co-precipitation method was much larger than that from a reverse co-precipitation method without addition of oil membrane layer.

Facile and cost-effective synthesis of CNT@MCo2O4 (M = Ni, Mn, Cu, Zn) core–shell hybrid nanostructures for organic dye removal

RSC Advances ◽  
2015 ◽  
Vol 5 (97) ◽  
pp. 79765-79773 ◽  
Author(s):  
Haizhen Li ◽  
Zebin Sun ◽  
Yaxi Tian ◽  
Guijia Cui ◽  
Shiqiang Yan
Keyword(s):  
Room Temperature ◽  
Dye Removal ◽  
Annealing Treatment ◽  
Cost Effective ◽  
Organic Dye ◽  
Hybrid Nanostructures ◽  
Deposition Method ◽  
Post Annealing ◽  
Simple Chemical ◽  
Effective Synthesis

This study presents four hybrid materials of CNT@MCo2O4 (M = Ni, Mn, Cu, Zn) which were prepared via a simple chemical bath deposition method at room temperature followed by a post-annealing treatment.

Experimental Study on Cost-Effective Additive Manufacturing of Silica Aerogel

2020 ◽  
Author(s):  
Zipeng Guo ◽  
Ruizhe Yang ◽  
Tianjiao Wang ◽  
Lu An ◽  
Shenqiang Ren ◽  
...  
Keyword(s):  
Thermal Insulation ◽  
Silica Aerogel ◽  
Low Cost ◽  
Ambient Pressure ◽  
Cost Effective ◽  
Supercritical Drying ◽  
Ambient Pressure Drying ◽  
Insulation Material ◽  
Market Demand ◽  
Insulation Property

Abstract The conventional manufacturing process of aerogel insulation material relies largely on the supercritical drying, which suffers from issues of massive energy consumption, high-cost equipment and prolonged processing time. With the consideration of large market demand of the aerogel insulation material in the next decade, a low-cost and scalable fabrication technique is highly desired. In this paper, a direct ink writing (DIW) method is used to three-dimensionally fabricate the silica aerogel insulation material, followed by room-temperature and ambient pressure drying. Compared to the supercritical drying and freeze-drying, the reported method significantly reduces the fabrication time and costs. The cost-effective DIW technique offers the capability to print complex hollow internal structures, coupled with the porous structure, is found to be beneficial to the thermal insulation property. The addition of fiber to the ink assures the durability of the fabricated product. The foam ink preparation methods and the printability are demonstrated in this paper, along with the printed samples for characterizing thermal insulation performance and mechanical properties.

Cost Effective Synthesis and Fabrication of Phase-Pure Kesterite Cu2-xZn1.3SnS4 P-type Absorber Layer Thin Films by Solvent Based Process Technique for Photovoltaic Solar Energy Applications

2018 ◽  
Vol 7 (4) ◽  
pp. 36
Author(s):  
B. Khadambari ◽  
S. S. Bhattacharya
Keyword(s):  
Solar Energy ◽  
Renewable Energy Sources ◽  
Cost Effective ◽  
Absorber Layer ◽  
Window Layer ◽  
Energy Applications ◽  
Process Technique ◽  
Absorber Material ◽  
Effective Synthesis ◽  
P Type

Solar has become one of the fastest growing renewable energy sources. With the push towards sustainability it is an excellent solution to resolve the issue of our diminishing finite resources. Alternative photovoltaic systems are of much importance to utilize solar energy efficiently. The Cu-chalcopyrite compounds CuInS2 and CuInSe2 and their alloys provide absorber material of high absorption coefficients of the order of 105 cm-1. Cu2ZnSnS4 (CZTS) is more promising material for photovoltaic applications as Zn and Sn are abundant materials of earth’s crust. Further, the preparation of CZTS-ink facilitates the production of flexible solar cells. The device can be designed with Al doped ZnO as the front contact, n-type window layer (e.g. intrinsic ZnO); an n-type thin film buffer layer (e.g. CdS) and a p-type CZTS absorber layer with Molybdenum (Mo) substrate as back contact. In this study, CZTS films were synthesized by a non-vaccum solvent based process technique from a molecular-ink using a non toxic eco-friendly solvent dimethyl sulfoxide (DMSO). The deposited CZTS films were optimized and characterized by XRD, UV-visible spectroscopy and SEM.

Naturally Occurring Organic Acid-catalyzed Facile Diastereoselective Synthesis of Biologically Active (E)-3-(arylimino)indolin-2-one Derivatives in Water at Room Temperature

2019 ◽  
Vol 23 (16) ◽  
pp. 1778-1788 ◽  
Author(s):  
Gurpreet Kaur ◽  
Arvind Singh ◽  
Kiran Bala ◽  
Mamta Devi ◽  
Anjana Kumari ◽  
...  
Keyword(s):  
Room Temperature ◽  
Biologically Active ◽  
Environmentally Benign ◽  
Diastereoselective Synthesis ◽  
Substituted Anilines ◽  
Reaction Conditions ◽  
Naturally Occurring ◽  
Acid Catalyzed ◽  
Reaction Media ◽  
Column Chromatographic

A simple, straightforward and efficient method has been developed for the synthesis of (E)-3-(arylimino)indolin-2-one derivatives and (E)-2-((4-methoxyphenyl)imino)- acenaphthylen-1(2H)-one. The synthesis of these biologically-significant scaffolds was achieved from the reactions of various substituted anilines and isatins or acenaphthaquinone, respectively, using commercially available, environmentally benign and naturally occurring organic acids such as mandelic acid or itaconic acid as catalyst in aqueous medium at room temperature. Mild reaction conditions, energy efficiency, good to excellent yields, environmentally benign conditions, easy isolation of products, no need of column chromatographic separation and the reusability of reaction media are some of the significant features of the present protocol.

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