Rhodium(I)-Catalyzed Asymmetric Addition of Organometallic Reagents to Unsaturated Compounds

2019 ◽  
pp. 85-116
Author(s):  
Hsyueh-Liang Wu ◽  
Ping-Yu Wu
Keyword(s):  
Asymmetric Addition ◽  
Organometallic Reagents ◽  
Unsaturated Compounds

ChemInform Abstract: Asymmetric Addition of Organometallic Reagents to Homochiral β-Ketoacetals.

ChemInform ◽  
1989 ◽  
Vol 20 (6) ◽  
Author(s):  
T. HOSOKAWA ◽  
T. YAGI ◽  
Y. ATAKA ◽  
S.-I. MURAHASHI
Keyword(s):  
Asymmetric Addition ◽  
Organometallic Reagents

Asymmetric Addition of Organometallic Reagents to O-Phenethyl Aldoximes

Synlett ◽  
1995 ◽  
Vol 1995 (05) ◽  
pp. 445-446 ◽  
Author(s):  
Peter T. Gallagher ◽  
Andrew P. Lightfood ◽  
Christopher J. Moody ◽  
Alexandra M. Z. Slawin
Keyword(s):  
Asymmetric Addition ◽  
Organometallic Reagents

ChemInform Abstract: Solvent Effect on Asymmetric Addition of Organometallic Reagents to Homochiral β-Ketoacetals.

ChemInform ◽  
1990 ◽  
Vol 21 (10) ◽  
Author(s):  
T. SUGITA ◽  
N. KOMATSU ◽  
T. TERADA ◽  
A. KURIHARA ◽  
T. KAGIYA
Keyword(s):  
Solvent Effect ◽  
Asymmetric Addition ◽  
Organometallic Reagents

scholarly journals Asymmetric Addition of Organometallic Reagents to Homochiral β-Ketoacetals

1988 ◽  
Vol 61 (9) ◽  
pp. 3380-3382 ◽  
Author(s):  
Takahiro Hosokawa ◽  
Tetsushi Yagi ◽  
Yoshiharu Ataka ◽  
Shun-Ichi Murahashi
Keyword(s):  
Asymmetric Addition ◽  
Organometallic Reagents

ChemInform Abstract: Asymmetric Addition of Organometallic Reagents to O-Phenethyl Aldoximes.

ChemInform ◽  
2010 ◽  
Vol 26 (39) ◽  
pp. no-no
Author(s):  
P. T. GALLAGHER ◽  
A. P. LIGHTFOOT ◽  
C. J. MOODY ◽  
A. M. Z. SLAWIN
Keyword(s):  
Asymmetric Addition ◽  
Organometallic Reagents

Enantioselective Multi-Component Cyclopropane Synthesis Enabled by Cu-Catalyzed Cyclopropene Carbometallation with Organoboron Reagent

2018 ◽  
Author(s):  
Zhanyu Li ◽  
Mengru Zhang ◽  
Yu Zhang ◽  
Shuang Liu ◽  
Jinbo Zhao ◽  
...  
Keyword(s):  
Carbon Source ◽  
Stereoselective Synthesis ◽  
Organometallic Reagents ◽  
Preliminary Results ◽  
Quaternary Center ◽  
Chiral Centers ◽  
Substituted Cyclopropanes ◽  
Proof Of Principle

Deployment of organoboron in lieu of the strongly basic <br>organometallic reagents as carbon source in Cu-catalyzed <br>cyclopropene carbometallation opens unprecedented three-<br>component reactivity for stereoselective synthesis of poly-substituted cyclopropanes. A proof-of-principle demonstration of this novel carbometallation strategy is presented herein for a highly convergent access to poly-substituted aminocyclopropane framework via <br>carboamination. Preliminary results on asymmetric desymmetrization with commercial bisphosphine ligands attained high levels of enantioselection, offering a straightforward access to enantioenriched aminocyclopropanes bearing all-three chiral centers, including an all-carbon quaternary center. This strategy may underpin a host of novel synthetic protocols for poly-substituted cyclopropanes. <br>

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