Functionalization of Nanotubes by Ring-Opening and Anionic Surface Initiated Polymerization

2011 ◽  
pp. 159-177
Author(s):  
Georgios Sakellariou ◽  
Dimitrios Priftis ◽  
Nikos Hadjichristidis
Keyword(s):  
Ring Opening ◽  
Surface Initiated Polymerization ◽  
Anionic Surface

Homopolymer and block copolymer brushes on gold by living anionic surface-initiated polymerization in a polar solvent

2005 ◽  
Vol 44 (2) ◽  
pp. 769-782 ◽  
Author(s):  
Georgios Sakellariou ◽  
Mikyoung Park ◽  
Rigoberto Advincula ◽  
Jimmy W. Mays ◽  
Nikos Hadjichristidis
Keyword(s):  
Block Copolymer ◽  
Polar Solvent ◽  
Surface Initiated Polymerization ◽  
Copolymer Brushes ◽  
Anionic Surface

Living Anionic Surface-Initiated Polymerization (LASIP) of a Polymer on Silica Nanoparticles

Langmuir ◽  
2002 ◽  
Vol 18 (8) ◽  
pp. 3324-3331 ◽  
Author(s):  
Qingye Zhou ◽  
Shuangxi Wang ◽  
Xiaowu Fan ◽  
Rigoberto Advincula ◽  
Jimmy Mays
Keyword(s):  
Silica Nanoparticles ◽  
Surface Initiated Polymerization ◽  
Anionic Surface

Polymer Brushes by Living Anionic Surface Initiated Polymerization on Flat Silicon (SiOx) and Gold Surfaces:  Homopolymers and Block Copolymers

Langmuir ◽  
2002 ◽  
Vol 18 (22) ◽  
pp. 8672-8684 ◽  
Author(s):  
Rigoberto Advincula ◽  
Qingye Zhou ◽  
Mikyoung Park ◽  
Shuangxi Wang ◽  
Jimmy Mays ◽  
...  
Keyword(s):  
Block Copolymers ◽  
Polymer Brushes ◽  
Gold Surfaces ◽  
Surface Initiated Polymerization ◽  
Anionic Surface

Living Anionic Surface-Initiated Polymerization (LASIP) of Styrene from Clay Nanoparticles Using Surface Bound 1,1-Diphenylethylene (DPE) Initiators

Langmuir ◽  
2002 ◽  
Vol 18 (11) ◽  
pp. 4511-4518 ◽  
Author(s):  
Xiaowu Fan ◽  
Qingye Zhou ◽  
Chuanjun Xia ◽  
Walter Cristofoli ◽  
Jimmy Mays ◽  
...  
Keyword(s):  
Clay Nanoparticles ◽  
Surface Initiated Polymerization ◽  
Anionic Surface

scholarly journals Multistep organic synthesis of modular photosystems

2012 ◽  
Vol 8 ◽  
pp. 897-904 ◽  
Author(s):  
Naomi Sakai ◽  
Stefan Matile
Keyword(s):  
Charge Transfer ◽  
Natural Product ◽  
Organic Synthesis ◽  
Ring Opening ◽  
Free Choice ◽  
Disulfide Exchange ◽  
Surface Initiated Polymerization ◽  
Complex Architectures ◽  
Target Molecules ◽  
Recent Synthesis

Quite extensive synthetic achievements vanish in the online supporting information of publications on functional systems. Underappreciated, their value is recognized by experts only. As an example, we here focus in on the recent synthesis of multicomponent photosystems with antiparallel charge-transfer cascades in co-axial hole- and electron-transporting channels. The synthetic steps are described one-by-one, starting with commercial starting materials and moving on to key intermediates, such as asparagusic acid, an intriguing natural product, as well as diphosphonate “feet”, and panchromatic naphthalenediimides (NDIs), to finally reach the target molecules. These products are initiators and propagators for self-organizing surface-initiated polymerization (SOSIP), a new method introduced to secure facile access to complex architectures. Chemoorthogonal to the ring-opening disulfide exchange used for SOSIP, hydrazone exchange is then introduced to achieve stack exchange, which is a “switching” technology invented to drill giant holes into SOSIP architectures and fill them with functional π-stacks of free choice.

Living Anionic Surface Initiated Polymerization (SIP) of Styrene from Clay Surfaces

2001 ◽  
Vol 13 (8) ◽  
pp. 2465-2467 ◽  
Author(s):  
Qingye Zhou ◽  
Xiaowu Fan ◽  
Chuanjun Xia ◽  
Jimmy Mays ◽  
Rigoberto Advincula
Keyword(s):  
Surface Initiated Polymerization ◽  
Anionic Surface
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