Thermodynamics of Concentration Cells

Use of strontium β-alumina based composite electrolyte in phosphorus concentration cells

Ionics ◽

10.1007/bf02375621 ◽

1997 ◽

Vol 3 (3-4) ◽

pp. 229-234 ◽

Cited By ~ 2

Author(s):

C. Wordsworth ◽

R. V. Kumar ◽

D. J. Fray

Keyword(s):

Phosphorus Concentration ◽

Composite Electrolyte ◽

Concentration Cells

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Do Concentration Cells Store Charge in Water? Comment on Can Water Store Charge?

Langmuir ◽

10.1021/la900723t ◽

2009 ◽

Vol 25 (11) ◽

pp. 6587-6589 ◽

Cited By ~ 12

Author(s):

Horacio R. Corti* ◽

Agustin J. Colussi

Keyword(s):

Do Concentration ◽

Concentration Cells

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An alternative methodology for determining transport parameters of electrolytes in mixed solvents from concentration cells, without prior knowledge of activity coefficients

Electrochemistry Communications ◽

10.1016/s1388-2481(99)00153-8 ◽

2000 ◽

Vol 2 (2) ◽

pp. 108-111 ◽

Cited By ~ 1

Author(s):

Patrizia R. Mussini ◽

Torquato Mussini

Keyword(s):

Prior Knowledge ◽

Activity Coefficients ◽

Mixed Solvents ◽

Transport Parameters ◽

Alternative Methodology ◽

Concentration Cells

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Is the Nernst Equation Applicable to Silver(I) Concentration Cells in Fused Nitrate Medium?.

Acta Chemica Scandinavica ◽

10.3891/acta.chem.scand.28a-0284 ◽

1974 ◽

Vol 28a ◽

pp. 284-288 ◽

Cited By ~ 5

Author(s):

Bertil Holmberg ◽

Yukiyoshi Sasaki ◽

A. M. Sargeson ◽

C. E. Schäffer ◽

Alf Bjørseth ◽

...

Keyword(s):

Nernst Equation ◽

Nitrate Medium ◽

Concentration Cells

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Thermodynamic Study of Tl6SBr4 Compound and Some Regularities in Thermodynamic Properties of Thallium Chalcohalides

Advances in Materials Science and Engineering ◽

10.1155/2017/5370289 ◽

2017 ◽

Vol 2017 ◽

pp. 1-9 ◽

Cited By ~ 1

Author(s):

Dunya Mahammad Babanly ◽

Qorkhmaz Mansur Huseynov ◽

Ziya Saxaveddin Aliev ◽

Dilgam Babir Tagiyev ◽

Mahammad Baba Babanly

Keyword(s):

Phase Diagram ◽

Thermodynamic Properties ◽

Thermodynamic Functions ◽

Chemical Bonding ◽

Electromotive Force ◽

Solid Phase ◽

Thermodynamic Study ◽

Degree Of Ionization ◽

Emf Measurements ◽

Concentration Cells

The solid-phase diagram of the Tl-TlBr-S system was clarified and the fundamental thermodynamic properties of Tl6SBr4 compound were studied on the basis of electromotive force (EMF) measurements of concentration cells relative to a thallium electrode. The EMF results were used to calculate the relative partial thermodynamic functions of thallium in alloys and the standard integral thermodynamic functions (-ΔfG0, -ΔfH0, and S0298) of Tl6SBr4 compound. All data regarding thermodynamic properties of thallium chalcogen-halides are generalized and comparatively analyzed. Consequently, certain regularities between thermodynamic functions of thallium chalcogen-halides and their binary constituents as well as degree of ionization (DI) of chemical bonding were revealed.

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XXIV.—On the Temperature Coefficient of Concentration Cells, in which the same salt is dissolved in two different solvents

Proceedings of the Royal Society of Edinburgh ◽

10.1017/s0370164600025219 ◽

1912 ◽

Vol 31 ◽

pp. 375-396

Author(s):

A. P. Laurie

Keyword(s):

Temperature Coefficient ◽

Potassium Iodide ◽

Royal Society ◽

Platinum Electrode ◽

The Other ◽

Absolute Alcohol ◽

Concentration Cell ◽

New Type ◽

The One ◽

Concentration Cells

In a paper read before the Royal Society of Edinburgh (Proc. Roy. Soc. Edin., xxviii., part v., p. 382 (1908); Zeit. phys. Chem., lxiv. 5) I described a new type of concentration cell, in which the one platinum electrode was surrounded by a solution of ·025 molecules of KI containing ·001 molecules of iodine dissolved in absolute alcohol, and the other electrode was surrounded by ·025 molecules of KI and ·001 molecules of iodine, dissolved in water. This cell developed a considerable E.M.F. of ·198 volts at 25° C. in the direction which would transfer the iodine from water to alcohol and potassium iodide from alcohol to water.

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