Electron Diffraction in Gases and Molecular Structure

2007 ◽  
pp. 323-362 ◽  
Author(s):  
O. Bastiansen ◽  
P. N. Skancke
Keyword(s):  
Molecular Structure ◽  
Electron Diffraction

Die Molekülstruktur des N-Chlorsdiwefeloxiddifluoridimids ClNSOF2 / The Molecular Structure of ClNSOF2

1974 ◽  
Vol 29 (6) ◽  
pp. 901-904 ◽  
Author(s):  
O. Oberhammer ◽  
O. Glemser ◽  
H. Klüver
Keyword(s):  
Molecular Structure ◽  
Electron Diffraction ◽  
Geometric Parameters ◽  
Mean Square ◽  
The Mean

The molecular structure of ClNSOF2 was determined by electron diffraction of gases. The following geometric parameters were obtained:Cl-N=1.715(5), S=N=1.484(7), S=O=1.394(3), S-F=1.548(3) Å, ∢ ClNS=114.7 (8), ∢ FSF=92.6(.8), ∢ NSF=111.8(.9) ∢ NSO=117.4 (3.1) and ∢ OSF=108.6 (.8)°. The results for the mean square amplitudes of vibration are given in the paper and an attempt is made to explain differences in corresponding parameters of some related molecules.

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