Bimetallic Oxidation Catalysts: Hydrogen Peroxide Generation and Its Use in Hydrocarbon Oxidation

2005 ◽  
pp. 187-199 ◽  
Author(s):  
Joseph E. Remias ◽  
Ayusman Sen
Keyword(s):  
Hydrogen Peroxide ◽  
Hydrocarbon Oxidation ◽  
Oxidation Catalysts ◽  
Hydrogen Peroxide Generation

Hydrogen Peroxide Generation with 100% Faradaic Efficiency on Metal-Free Carbon Black

ACS Catalysis ◽  
2021 ◽  
Vol 11 (4) ◽  
pp. 2454-2459
Author(s):  
Zhe Wang ◽  
Qin-Kun Li ◽  
Chenhao Zhang ◽  
Zhihua Cheng ◽  
Weiyin Chen ◽  
...  
Keyword(s):  
Hydrogen Peroxide ◽  
Carbon Black ◽  
Free Carbon ◽  
Faradaic Efficiency ◽  
Metal Free ◽  
Hydrogen Peroxide Generation

scholarly journals Peroxiredoxin 2 oxidation reveals hydrogen peroxide generation within erythrocytes during high-dose vitamin C administration

Redox Biology ◽  
2021 ◽  
Vol 43 ◽  
pp. 101980
Author(s):  
Andree G. Pearson ◽  
Juliet M. Pullar ◽  
John Cook ◽  
Emma S. Spencer ◽  
Margreet CM. Vissers ◽  
...  
Keyword(s):  
Hydrogen Peroxide ◽  
Vitamin C ◽  
High Dose ◽  
Peroxiredoxin 2 ◽  
Hydrogen Peroxide Generation ◽  
High Dose Vitamin

Copper-Containing SiCN Precursor Ceramics (Cu@SiCN) as Selective Hydrocarbon Oxidation Catalysts Using Air as an Oxidant

2010 ◽  
Vol 16 (14) ◽  
pp. 4231-4238 ◽  
Author(s):  
Germund Glatz ◽  
Thomas Schmalz ◽  
Tobias Kraus ◽  
Frank Haarmann ◽  
Günter Motz ◽  
...  
Keyword(s):  
Hydrocarbon Oxidation ◽  
Oxidation Catalysts

scholarly journals Hydrogen Peroxide Generation Induces pp60srcActivation in Human Platelets

2003 ◽  
Vol 279 (3) ◽  
pp. 1665-1675 ◽  
Author(s):  
Juan A. Rosado ◽  
Pedro C. Redondo ◽  
Ginés M. Salido ◽  
Emilio Gómez-Arteta ◽  
Stewart O. Sage ◽  
...  
Keyword(s):  
Hydrogen Peroxide ◽  
Human Platelets ◽  
Hydrogen Peroxide Generation

μ-Oxo diferric complexes as oxidation catalysts with hydrogen peroxide and their potential in asymmetric oxidation

1997 ◽  
Vol 38 (21) ◽  
pp. 3727-3730 ◽  
Author(s):  
Carole Duboc-Toia ◽  
Stéphane Ménage ◽  
Claude Lambeaux ◽  
Marc Fontecave
Keyword(s):  
Hydrogen Peroxide ◽  
Oxidation Catalysts ◽  
Asymmetric Oxidation

Hydrogen Peroxide Generation by Eosinophils in Allergic Rhinitis

1991 ◽  
Vol 18 (2) ◽  
pp. 133-143 ◽  
Author(s):  
Hiroshi Ogasawara ◽  
Shiro Yoshimura ◽  
Takeo Kumoi
Keyword(s):  
Hydrogen Peroxide ◽  
Allergic Rhinitis ◽  
Hydrogen Peroxide Generation

scholarly journals Multienzymatic in situ hydrogen peroxide generation cascade for peroxygenase-catalysed oxyfunctionalisation reactions

2019 ◽  
Vol 74 (3-4) ◽  
pp. 101-104 ◽  
Author(s):  
Milja Pesic ◽  
Sébastien Jean-Paul Willot ◽  
Elena Fernández-Fueyo ◽  
Florian Tieves ◽  
Miguel Alcalde ◽  
...  
Keyword(s):  
Hydrogen Peroxide ◽  
Formate Dehydrogenase ◽  
Flavin Mononucleotide ◽  
Candida Boidinii ◽  
Reaction Parameters ◽  
Old Yellow Enzyme ◽  
Hydroxylation Reaction ◽  
In Situ Generation ◽  
Hydrogen Peroxide Generation

Abstract There is an increasing interest in the application of peroxygenases in biocatalysis, because of their ability to catalyse the oxyfunctionalisation reaction in a stereoselective fashion and with high catalytic efficiencies, while using hydrogen peroxide or organic peroxides as oxidant. However, enzymes belonging to this class exhibit a very low stability in the presence of peroxides. With the aim of bypassing this fast and irreversible inactivation, we study the use of a gradual supply of hydrogen peroxide to maintain its concentration at stoichiometric levels. In this contribution, we report a multienzymatic cascade for in situ generation of hydrogen peroxide. In the first step, in the presence of NAD+ cofactor, formate dehydrogenase from Candida boidinii (FDH) catalysed the oxidation of formate yielding CO2. Reduced NADH was reoxidised by the reduction of the flavin mononucleotide cofactor bound to an old yellow enzyme homologue from Bacillus subtilis (YqjM), which subsequently reacts with molecular oxygen yielding hydrogen peroxide. Finally, this system was coupled to the hydroxylation of ethylbenzene reaction catalysed by an evolved peroxygenase from Agrocybe aegerita (rAaeUPO). Additionally, we studied the influence of different reaction parameters on the performance of the cascade with the aim of improving the turnover of the hydroxylation reaction.

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