Water Saturated Column Experiments for the Determination of Mobilizable Inorganic Pollutants from Loose Material

Vom Wasser ◽  
2003 ◽  
pp. 49-60 ◽  
Author(s):  
Markus Delay ◽  
Daniel Schmitt ◽  
Fritz Hartmann Frimmel
InterConf ◽  
2021 ◽  
pp. 917-933
Author(s):  
Аkbota Serikkyzy ◽  
A. Baimakhan ◽  
A. Makhanova ◽  
Baimakhan Baimakhan ◽  
G. Baimakhanova

The results of theoretical and experimental works devoted to the determination of the physical and mechanical properties of water–saturated soil are analyzed. On the basis of a comprehensive analysis, conclusions are formulated, and a method is proposed for determining the Young’s modulus and Poisson’s ratio for water-saturated soil, depending on humidity (degree of saturation) and porosity. Tables of data on the physical and mechanical properties of water–saturated soil are proposed. The study established the places of formation of local stress concentrations along the inclined layer. The values of dangerous stress concentrations found in various areas of the mountain slope that are vulnerable to collapse are shown in the tables.


1980 ◽  
Vol 63 (3) ◽  
pp. 631-633 ◽  
Author(s):  
James E Thean ◽  
David R Lorenz ◽  
David M Wilson ◽  
Kathleen Rodgers ◽  
Richard C Gueldner

Abstract A method is proposed for extraction and cleanup of corn samples for the quantitation of 4 aflatoxins by high pressure liquid chromatography (HPLC). After aqueous methanol extraction, ammonium sulfate treatment, and partition of aflatoxins into chloroform, sample extracts are partially purified on Sep-Pak cartridges or small columns packed with HPLC grade silica; cleanup requires only 13 mL solvent/sample. Aflatoxins B1, B2, G1, and G2 in the purified extract are resolved in ca 10 min by normal phase HPLC on a microparticulate (5 μm) silica gel column with a 50% water-saturated chloroform-cyclohexaneacetonitrile- ethanol solvent, and are measured by ultraviolet fluorescence in a silica gel-packed flowcell. Recoveries of added aflatoxins B1, B2, G1, and G2 were 84–118 % at levels of 1.5–125 μg/kg


Author(s):  
Mariana Silveira Guerra Moura e Silva ◽  
Ana Lúcia Silva Marigo ◽  
William Viveiros ◽  
Mônica Luisa Kuhlmann

The midge Chironomus sancticaroli (Diptera: Chironomidae) has been used in ecotoxicological tests because it is sensitive to a variety of inorganic pollutants. Among the parameters used to evaluate the toxicity of a substance is the frequency of mentum deformity, which is part of the oral system of this organism. However, there is still no consensus on the baseline level (percentage) of acceptable deformities in laboratory cultures not exposed to pollutants. The determination of this variable is important to ensure the validity of bioassays and to compare cultures from different research and teaching institutions. Once this value is established, it will also be used to monitor the quality of organisms cultured, since factors such as inbreeding could increase the frequency of mentum deformity. Thus, the objective of this study was to quantify the percentage of mentum deformity in the fourth instar of C. sancticaroli larvae from the culture of the Laboratory of Aquatic Ecosystems, at Embrapa Meio Ambiente. The average frequency of mentum deformity obtained was 6,63%. It is believed that factors such as the renewal of the culture with the inclusion of spawns from the laboratories of other institutions, as well as the control of the quality of the dilution water and the sediment of the breeding may have contributed to a low frequency of mentum deformity of the culture observed in this study.


2007 ◽  
Vol 4 (5) ◽  
pp. 293 ◽  
Author(s):  
Dawn M. Wellman ◽  
Eric M. Pierce ◽  
Michelle M. Valenta

Environmental context. Contamination of groundwater and sediments by heavy metals and radioactive metals is a significant problem within the United States Department of Energy complex as a result of past nuclear operations. One way to remediate these metals is through reaction with phosphate compounds, which can immobilise the metals by forming highly stable metal phosphate compounds. Long-chain, water-soluble phosphate compounds provide a means to inject phosphate into subsurface contaminant plumes, to precipitate metal ions from solution. Results presented here illustrate that application of a soluble sodium tripolyphosphate to sediment contaminated with uranium will rapidly reduce the concentration of uranium in the pore water to concentrations near or below drinking water limits under water-saturated and unsaturated conditions. Abstract. A series of conventional water-saturated and pressurised unsaturated flow column experiments were conducted to evaluate the effects of using soluble polyphosphate amendments for in-situ, subsurface remediation of uranium. Experiments were conducted under mildly alkaline, calcareous conditions, representative of conditions commonly encountered at sites across the arid western United States. Results presented here illustrate that application of a soluble polyphosphate amendment to sediment contaminated with uranium will rapidly reduce the concentration of uranium released to the porewater to near or below drinking water limits under water-saturated and -unsaturated conditions. Column experiments conducted in the absence of polyphosphate illustrate sustained release of aqueous uranium at concentrations well above drinking water standards in excess of over 25 pore volumes under water-saturated conditions and over 50 pore volumes under unsaturated conditions. In the presence of tripolyphosphate, the concentration of aqueous uranium released from the sediment was below drinking water limits within 10 to 35 pore volumes under water-saturated and unsaturated conditions, respectively. Moreover, results indicate the necessity of conducting site-specific dynamic tests to tailor phosphate-based remediation technology to site specific geochemical and hydrological conditions.


Geophysics ◽  
1956 ◽  
Vol 21 (3) ◽  
pp. 739-754 ◽  
Author(s):  
Warren G. Hicks ◽  
James E. Berry

Recent studies of continuous acoustic velocity logs indicate that these logs may provide important assistance in differentiating gas, oil, and water saturations in reservoir rocks. In general, velocities are appreciably lower in sands carrying oil or gas than in water‐saturated sands of otherwise similar character. Specific examples from field logs illustrate this application. Laboratory measurements have been made of acoustic velocity of synthetic and natural rocks. Published studies, both empirical and theoretical, of other workers concerned with the transmission of sound in porous media have been considered. All of these at least qualitatively confirm the conclusions drawn from field data.


1988 ◽  
Vol 127 ◽  
Author(s):  
J. A. Del Debbio ◽  
T. R. Thomas

ABSTRACTLaboratory studies are being conducted to measure the transport properties of various radionuclide species through soil columns. The studies are being conducted to support evaluations for potential near-surface disposal of high-level radioactive waste (HLW) calcine stored at the Idaho National Engineering Laboratory. The data will be used to model radionuclide transport through the vadose (unsaturated) zone of the site under various water-contact scenarios. Retardation factors and dispersion coefficients for technetium and selenium species have been measured in water-saturated soil columns made up of sediments taken from 12 and 35 meters below the surface. A one-dimensional, convective-dispersive, solute-transport equation was fitted to column effluent data by optimizing three parameters (retardation factor, dispersion coefficient and pulse time) using a non-linear, least-squares fitting routine. The data indicated no retardation of the pertechnetate ion (TcO4-)and selenate ion (SeO4-) and a large retardation of the selenite ion (SeO3-) relative to water transport through the soil column.


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