Photomagnetic Properties of Some Inorganic Solids

2003 ◽  
pp. 257-295 ◽  
Author(s):  
François Varret ◽  
Marc Nogues ◽  
Antoine Goujon
Keyword(s):  
Inorganic Solids

Bio-Nanohybrids Based on Layered Inorganic Solids: Gelatin Nanocomposites

2006 ◽  
Vol 2 (3) ◽  
pp. 231-241 ◽  
Author(s):  
Margarita Darder ◽  
Ana Isabel Ruiz ◽  
Pilar Aranda ◽  
Henri Van Damme ◽  
Eduardo Ruiz-Hitzky
Keyword(s):  
Inorganic Solids

scholarly journals Development of Efficient and Selective Processes for the Synthesis of Commercially Important Chlorinated Phenols

Organics ◽  
2021 ◽  
Vol 2 (3) ◽  
pp. 142-160
Author(s):  
Keith Smith ◽  
Gamal A. El-Hiti
Keyword(s):  
Lewis Acid ◽  
Large Scale ◽  
Commercial Application ◽  
Chlorinated Phenols ◽  
Sulphur Compounds ◽  
Inorganic Solids ◽  
Solvent Free Conditions ◽  
Commercially Important ◽  
Ortho Cresol ◽  
Very High

para-Selective processes for the chlorination of phenols using sulphuryl chloride in the presence of various sulphur-containing catalysts have been successfully developed. Several chlorinated phenols, especially those derived by para-chlorination of phenol, ortho-cresol, meta-cresol, and meta-xylenol, are of significant commercial importance, but chlorination reactions of such phenols are not always as regioselective as would be desirable. We, therefore, undertook the challenge of developing suitable catalysts that might promote greater regioselectivity under conditions that might still be applicable for the commercial manufacture of products on a large scale. In this review, we chart our progress in this endeavour from early studies involving inorganic solids as potential catalysts, through the use of simple dialkyl sulphides, which were effective but unsuitable for commercial application, and through a variety of other types of sulphur compounds, to the eventual identification of particular poly(alkylene sulphide)s as very useful catalysts. When used in conjunction with a Lewis acid such as aluminium or ferric chloride as an activator, and with sulphuryl chloride as the reagent, quantitative yields of chlorophenols can be obtained with very high regioselectivity in the presence of tiny amounts of the polymeric sulphides, usually in solvent-free conditions (unless the phenol starting material is solid at temperatures even above about 50 °C). Notably, poly(alkylene sulphide)s containing longer spacer groups are particularly para-selective in the chlorination of m-cresol and m-xylenol, while, ones with shorter spacers are particularly para-selective in the chlorination of phenol, 2-chlorophenol, and o-cresol. Such chlorination processes result in some of the highest para/ortho ratios reported for the chlorination of phenols.

A model of laser ablation in nonmetallic inorganic solids

1993 ◽  
Vol 73 (7) ◽  
pp. 3158-3162 ◽  
Author(s):  
Akiko Okano ◽  
Anne Y. Matsuura ◽  
Ken Hattori ◽  
Noriaki Itoh ◽  
Jai Singh
Keyword(s):  
Laser Ablation ◽  
Inorganic Solids

Spontaneous assembly and real-time growth of micrometre-scale tubular structures from polyoxometalate-based inorganic solids

2009 ◽  
Vol 1 (1) ◽  
pp. 47-52 ◽  
Author(s):  
Chris Ritchie ◽  
Geoffrey J. T. Cooper ◽  
Yu-Fei Song ◽  
Carsten Streb ◽  
Huabing Yin ◽  
...  
Keyword(s):  
Real Time ◽  
Tubular Structures ◽  
Inorganic Solids
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