Influence of the North American monsoon on Southern California tropospheric ozone levels during summer in 2013 and 2014

2017 ◽  
Vol 44 (12) ◽  
pp. 6431-6439 ◽  
Author(s):  
Maria Jose Granados-Muñoz ◽  
Matthew S. Johnson ◽  
Thierry Leblanc
Ecohydrology ◽  
2008 ◽  
Vol 1 (3) ◽  
pp. 225-238 ◽  
Author(s):  
Enrique R. Vivoni ◽  
Alex J. Rinehart ◽  
Luis A. Méndez-Barroso ◽  
Carlos A. Aragón ◽  
Gautam Bisht ◽  
...  

2015 ◽  
Vol 15 (12) ◽  
pp. 6943-6958 ◽  
Author(s):  
E. Crosbie ◽  
J.-S. Youn ◽  
B. Balch ◽  
A. Wonaschütz ◽  
T. Shingler ◽  
...  

Abstract. A 2-year data set of measured CCN (cloud condensation nuclei) concentrations at 0.2 % supersaturation is combined with aerosol size distribution and aerosol composition data to probe the effects of aerosol number concentrations, size distribution and composition on CCN patterns. Data were collected over a period of 2 years (2012–2014) in central Tucson, Arizona: a significant urban area surrounded by a sparsely populated desert. Average CCN concentrations are typically lowest in spring (233 cm−3), highest in winter (430 cm−3) and have a secondary peak during the North American monsoon season (July to September; 372 cm−3). There is significant variability outside of seasonal patterns, with extreme concentrations (1 and 99 % levels) ranging from 56 to 1945 cm−3 as measured during the winter, the season with highest variability. Modeled CCN concentrations based on fixed chemical composition achieve better closure in winter, with size and number alone able to predict 82 % of the variance in CCN concentration. Changes in aerosol chemical composition are typically aligned with changes in size and aerosol number, such that hygroscopicity can be parameterized even though it is still variable. In summer, models based on fixed chemical composition explain at best only 41 % (pre-monsoon) and 36 % (monsoon) of the variance. This is attributed to the effects of secondary organic aerosol (SOA) production, the competition between new particle formation and condensational growth, the complex interaction of meteorology, regional and local emissions and multi-phase chemistry during the North American monsoon. Chemical composition is found to be an important factor for improving predictability in spring and on longer timescales in winter. Parameterized models typically exhibit improved predictive skill when there are strong relationships between CCN concentrations and the prevailing meteorology and dominant aerosol physicochemical processes, suggesting that similar findings could be possible in other locations with comparable climates and geography.


2008 ◽  
Vol 35 (22) ◽  
Author(s):  
Enrique R. Vivoni ◽  
Hernan A. Moreno ◽  
Giuseppe Mascaro ◽  
Julio C. Rodriguez ◽  
Christopher J. Watts ◽  
...  

2018 ◽  
Author(s):  
Thierry Leblanc ◽  
Mark A. Brewer ◽  
Patrick S. Wang ◽  
Maria Jose Granados-Munoz ◽  
Kevin B. Strawbridge ◽  
...  

Abstract. The North-America-based Tropospheric Ozone Lidar Network (TOLNet) was recently established to provide high spatio-temporal vertical profiles of ozone, to better understand physical processes driving tropospheric ozone variability, and to validate the tropospheric ozone measurements of upcoming space-borne missions such as Tropospheric Emissions: Monitoring Pollution (TEMPO). The network currently comprises six tropospheric ozone lidars, four of which are mobile instruments deploying to the field a few times per year, based on campaign and science needs. In August 2016, all four mobile TOLNet lidars were brought to the fixed TOLNet site of JPL-Table Mountain Facility for the one-week-long Southern California Ozone Observation Project (SCOOP). This inter-comparison campaign, which included 400 hours of lidar measurements and 18 ozonesondes launches, allowed for the unprecedented simultaneous validation of five of the six TOLNet lidars. For measurements between 3 and 10 km above sea level, a mean difference of 0.7 ppbv (1.7 %), with a root-mean-square deviation of 1.6 ppbv or 2.4 % was found between the lidars and ozonesondes, which is well within the combined uncertainties of the two measurement techniques. The few minor differences identified were typically associated with the known limitations of the lidars at the profiles altitude extremes (i.e., first 1 km above ground and at the instruments highest retrievable altitude). As part of a large homogenization and quality control effort within the network, many aspects of the TOLNet in-house data processing algorithms were also standardized and validated. This thorough validation of both the measurements and retrievals builds confidence in the high quality and reliability of the TOLNet ozone lidar profiles for many years to come, making TOLNet a valuable ground-based reference network for tropospheric ozone profiling.


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