Nuclear Relaxation in Molecular Systems with Anisotropic Motions

2005 ◽  
pp. 69-80
Keyword(s):  
Nuclear Relaxation ◽  
Molecular Systems

A new classical method for dynamical calculation in molecular systems

1997 ◽  
Vol 90 (4) ◽  
pp. 599-609 ◽  
Author(s):  
NAĐA DOSLIC ◽  
S.DANKO BOSANAC
Keyword(s):  
Classical Method ◽  
Molecular Systems ◽  
Dynamical Calculation

Nuclear relaxation and electronic correlations in quasi-one-dimensional organic conductors. II. Experiments

1993 ◽  
Vol 3 (1) ◽  
pp. 171-201 ◽  
Author(s):  
P. Wzietek ◽  
F. Creuzet ◽  
C. Bourbonnais ◽  
D. Jérome ◽  
K. Bechgaard ◽  
...  
Keyword(s):  
Organic Conductors ◽  
Nuclear Relaxation ◽  
Electronic Correlations ◽  
One Dimensional

Nuclear relaxation in one-dimensional triplet-exciton systems

1982 ◽  
Vol 43 (4) ◽  
pp. 663-673 ◽  
Author(s):  
J.P. Travers ◽  
M. Gugliehni ◽  
M. Nechtschein
Keyword(s):  
Triplet Exciton ◽  
Nuclear Relaxation ◽  
One Dimensional

NUCLEAR RELAXATION OF Ag109m IN IRON DETECTED BY NUCLEAR ORIENTATION

1971 ◽  
Vol 32 (C1) ◽  
pp. C1-897-C1-898 ◽  
Author(s):  
N. J. STONE ◽  
R. A. FOX ◽  
F. HARTMANN-BOUTRON ◽  
D. SPANJAARD
Keyword(s):  
Nuclear Orientation ◽  
Nuclear Relaxation

Host-Guest Interactions on Electrode Surfaces for Immobilization of Molecular Catalysts

2020 ◽  
Author(s):  
Laurent Sévery ◽  
Jacek Szczerbiński ◽  
Mert Taskin ◽  
Isik Tuncay ◽  
Fernanda Brandalise Nunes ◽  
...  
Keyword(s):  
Aqueous Media ◽  
Heterogeneous Systems ◽  
Catalytic Systems ◽  
New Approach ◽  
Molecular Systems ◽  
Electrode Surfaces ◽  
Catalytic Surfaces ◽  
Oxide Electrodes ◽  
The Stability ◽  
Molecular Catalysts

The strategy of anchoring molecular catalysts on electrode surfaces combines the high selectivity and activity of molecular systems with the practicality of heterogeneous systems. The stability of molecular catalysts is, however, far less than that of traditional heterogeneous electrocatalysts, and therefore a method to easily replace anchored molecular catalysts that have degraded could make such electrosynthetic systems more attractive. Here, we apply a non-covalent “click” chemistry approach to reversibly bind molecular electrocatalysts to electrode surfaces via host-guest complexation with surface-anchored cyclodextrins. The host-guest interaction is remarkably strong and allows the flow of electrons between the electrode and the guest catalyst. Electrosynthesis in both organic and aqueous media was demonstrated on metal oxide electrodes, with stability on the order of hours. The catalytic surfaces can be recycled by controlled release of the guest from the host cavities and readsorption of fresh guest. This strategy represents a new approach to practical molecular-based catalytic systems.

Sign in / Sign up

Export Citation Format

Share Document